The intrinsic property that signifies an unstable molecular structure prone to rapid decomposition and energy release, beyond simple flammability, is its heat of decomposition.
Flammability refers to a substance's ability to burn or ignite easily, requiring an external ignition source and oxygen. Explosives, however, possess an inherent instability that allows them to decompose very rapidly, releasing a large amount of energy and gas without needing external oxygen. This rapid decomposition is the core of an explosion.
Heat of decomposition is the amount of energy (heat) released when a substance breaks....
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