In chemical storage, what fundamental principle dictates the separation of oxidizing agents from flammable liquids to prevent a dangerous reaction?

The fundamental principle dictating the separation of oxidizing agents from flammable liquids in chemical storage is the prevention of spontaneous combustion and uncontrolled fire. An oxidizing agent is a substance that readily donates oxygen atoms to another substance, thereby causing that other substance to react more rapidly, often with the release of heat. A flammable liquid is a liquid that easily ignites and burns rapidly, typically due to its low flash point. The flash point is the lowest temperature at which a liquid can form an ignitable mixture in air. When an oxidizing agent comes into direct contact with a flammable liquid, it can provide the oxygen necessary for combustion even in the absence of air. This bypasses the need for an external ignition source and can lead to a self-sustaining, rapid chemical reaction that generates significant heat and flame. This uncontrolled reaction is often referred to as spontaneous combustion or autoignition. To prevent this dangerous scenario, oxidizing agents and flammable liquids are stored separately. This separation ensures that if one material were to leak or spill, it would not immediately come into contact with a substance that could fuel its rapid and uncontrolled combustion.